Using a bithiazole complex as precursor to synthesis of CdO-CdS nanocomposite via direct thermal decomposition

Hosseinian, A.; Mahjoub, A.R.; Movahedi, M.

doi:10.7508/ijnd.2010.0x.007

Using a bithiazole complex as precursor to synthesis of CdO-CdS nanocomposite via direct thermal decomposition

Document Type : Reasearch Paper

Authors

¹ Department of Engineering Science, Faculty of Engineering, University of Tehran,Tehran, Iran.

² Department of chemistry, Tarbiat Modares University,Tehran ,Iran

³ Department of Chemistry, Payame Noor University, Isfahan, Iran.

10.7508/ijnd.2010.0x.007

Abstract

A new tris-chelate Cd(II) complex, [Cd(DADMBTZ)3](ClO3)2 has been successfully synthesized and characterized by IR, 1H, 13C NMR spectroscopy, elemental analysis and single crystal X-ray determination. The thermal behavior, UV-Vis and fluorescence spectra of compound were studied. In reaction with DADMBTZ, Cadmium (II) forms a tris-chelate complex with nearly C3 symmetry for coordination polyhedron, DADMBTZ acts as a bidentate ligand. In complex the ClO3 - anions are symmetrically different. Complex makes 2-D and 3-D networks via N-H…O and N-H…N hydrogen bonds, respectively. The nanocomposite CdO-CdS have been prepared using [Cd(DADMBTZ)3](ClO3)2 as precursor via thermal decomposition. As-prepared CdO-CdS nanocomposite was characterized By X-ray diffraction measurements (XRD), scanning electron microscopy (SEM).

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