Comparison of different kinetic models for adsorption of acid blue 62 as an environmental pollutant from aqueous solution onto mesoporous Silicate SBA-15 modified by Tannic acid

Document Type : Reasearch Paper

Authors

• Alireza Golshan Tafti ¹
• Abosaeed Rashidi ¹
• Habib-Allah Tayebi ²
• Mohammad Esmail Yazdanshenas ³

¹ Department of Textile Engineering, Science and Research Branch, Islamic Azad University, Tehran, Iran.

² Department of Textile Engineering, Qaemshahr Branch, Islamic Azad University, Qaemshahr, Iran.

³ Department of Textile Engineering, Yazd Branch, Islamic Azad University, Yazd, Iran.

Abstract

In this work, adsorption kinetics were investigated in order to remove the acid blue 62 off the aqueous solutions using mesoporous silicate SBA-15 loaded with tannic acid (tannin-SBA-15). Nitrogen adsorption and desorption test (BET), X-ray diffraction (XRD) and Fourier transform infra-red spectroscopy (FT-IR) analysis characterize synthesized composite. The impacts of some parameters such as PH, adsorbent dosage as well as contact time were studied and optimized at temperatures between 25 to 45 ^oC. The study also was conducted on intra-particle diffusion, pseudo first-order, pseudo second-order and Elovich kinetic models. In order to have the best correlation with the experimental data, the model of the second-order kinetics was discovered. The model of the intra-particle diffusion represents that both boundary layer and intra-particle diffusion processes control the mechanisms of adsorption of acid blue 62 onto tannin-SBA-15. 

Keywords

• Acid blue 62
• Adsorption
• Adsorption kinetic model
• SBA-15
• Tannic acid

20.1001.1.20088868.2018.9.1.9.3

Main Subjects

• Green Nanotechnology
• Nanostructured Materials
• Nanotechnology in Ecology and environmental Science

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References

[1] Binaeian E., Seghatoleslami N., Chaichi M. J., (2016), Synthesis of oak gall tannin-immobilized hexagonal mesoporous silicate (OGT-HMS) as a new super adsorbent for the removal of anionic dye from aqueous solution. Desalin. Water. Treat. 57: 8420–8436.

[2] Aksu Z., Isoglu I. A., (2006), Use of agricultural waste sugar beet pulp for the removal of Gemazol turquoise blue-G reactive dye from aqueous solution. J. Hazard. Mater. B137: 418–430.

[3] Baek M. H., Ijagbemi C. O., Kim D. S., (2010), Removal of malachite green from aqueous solution using degreased coffee bean. J. Hazard. Mater. 176: 820–828.

[4] Hameed B. H., Ahmad A. A., (2009), Batch adsorption of methylene blue from aqueous solution by garlic peel, an   agricultural waste biomass. J. Hazard. Mater. 164: 870–875.

[5] Hameed B. H., El-Khaiary M. I., (2008), Removal of basic dye from aqueous medium using a novel agricultural waste material: Pumpkin seed hull. J. Hazard. Mater. 155: 601–609.

[6] Akar T., Tosun I., Kaynak Z., Ozkara E., Yeni O., Sahin E. N., Akar S. T., (2009), An attractive agro-industrial by- product in environmental cleanup: Dye biosorption potential of untreated olive pomace. J. Hazard. Mater. 166: 1217–1225.

[7] Khaled A., El-Nemr A., El-Sikaily A., Abdelwahab O., (2009), Removal of direct N Blue-106 from artificial textile dye effluent using activated carbon from orange peel: Adsorption isotherm and kinetic studies. J. Hazard. Mater. 165: 100–110.

[8] Gupta N., Kushwaha A. K., Chattopadhyaya M. C., (2011), Application of potato (Solanum tuberosum) plant wastes for the removal of methylene blue and malachite green dye from solution. Arab. J. Chem. 9: S707-716.

[9] Tunc O., Tanacı H., Aksu Z., (2009), Potential use of cotton plant wastes for the removal of Remazol Black B reactive dye. J. Hazard. Mater. 163: 187–198.

[10] Ozacar M., Sengil I. A., Turkmenler H., (2008), Equilibrium and kinetic data and adsorption mechanism for adsorption of lead onto valonia tannin resin. Chem. Eng. J. 143: 32–42.

[11] Bagda E., (2012), The feasibility of using Rosa canina galls as an effective new biosorbent for removal of methylene blue and crystal violet. Desalin. Water. Treat. 43: 63-75.

[12] Yurtsever M., Sengil I. A., (2009), Biosorption of Pb (II) ions by modified quebracho tannin resin. J. Hazard. Mater. 163: 58–64.

[13] Shafiabadi M., Dasht A., Tayebi H. A., (2016), Removal of Hg (II) from aqueous solution using polypyrrole/SBA-15 nanocomposite: Experimental and modeling. Synth. Metal. 212: 154–160.

[14] Gao Q., Zhu H., Luo W. J.  , Wang S., Zhou C. G., (2014), Preparation, characterization, and adsorption evaluation of chitosan-functionalized mesoporous composites. Microporous. Mesoporous. Mater. 193: 15–26.

[15] Asouhidou D., Triantafyllidis K. S., Lazaridis N. K., Matis K. A., (2009), Adsorption of remazol Red 3BS from aqueous solutions using APTES- and cyclodextrin-modified HMS-type mesoporous silicas. Colloids Surf. A. 346: 83–90.

[16] Torabinejad A., Nasirizadeh N., Yazdanshenas M. E., Tayebi H. A., (2016), Synthesize and characterization of Aminosilane functionalized MCM-41 for removal of anionic dye: Kinetic and thermodynamic study. Int. J. Nano. Dimens. 7: 295-307.

[17] Huang X., Liao X., Shi B., (2010), Tannin-immobilized mesoporous silica bead (BT–SiO₂) as an effective adsorbent of Cr (III) in aqueous solutions. J. Hazard. Mater. 173: 33–39.

[18] Zhao D., Huo Q., Feng J., Chmelka B. F., Stucky G. D., (1998), Nonionic triblock and star diblock copolymer and oligomeric surfactant syntheses of highly ordered, hydrothermally stable, mesoporous silica structures. J. Am. Chem. Soc. 120: 6024–6036.

[19] Huang X., Wang Y., Liao X., Shi B., (2010), Adsorptive recovery of Au³⁺ from aqueous solutions using bayberry tannin-immobilized mesoporous silica. J. Hazard. Mater. 183: 793–798.

[20] Falcao L., Eduarda M., Araujo M., (2013), Tannins characterization in historic leathers by complementary analytical techniques ATR-FTIR, UV-Vis and chemical tests. J. Cultural. Heritage. 14: 499–508.

[21] Grishechko L. I., Amaral-Labat G., Szczurek A., Fierro V., Kuznetsov B. N., Pizzi A., Celzard A., (2013), New tannin–lignin aerogels. Ind. Crops Prod. 41: 347– 355.

[22] Bulut M. C. E., Ornek A., Ozacar M., (2013), Synthesis and characterization of valonea tannin resin and its interaction with palladium (II), rhodium (III) chloro complexes. Chem. Eng. J. 221: 146–158.

[23] Gurung M., Adhikari B. B., Kawakita H., Ohto K., Inoue K., Alam S., (2011), Recovery of Au(III) by using low cost adsorbent prepared from persimmon tannin Extract. Chem. Eng. J. 174: 556– 563.

[24] Yurtsever M., Sengil I. A., (2012), Adsorption and desorption behavior of silver ions onto valonia tannin resin. Trans. Nonferrous Met. Soc. China. 22: 2846-2854.

[25] Liu J., Ma S., Zang L., (2013), Preparation and characterization of ammonium-functionalized silica nanoparticle as a new adsorbent to remove methyl orange from aqueous solution. Appl. Surf. Sci. 265: 393– 398.

[26] Rahman M., Akter N., Karim M. R., Ahmad N., Rahman M. M.,  Siddiquey I. A., Bahadur N. M., Hasnat M. A., (2014), Optimization, kinetic and thermodynamic studies for removal of Brilliant Red (X-3B) using Tannin gel. J .Environ. Chem. Eng. 2: 76–83.

[27] Kumar P. S., Ramalingam S., Senthamarai C., Niranjanaa M., Vijayalakshmi P., Sivanesan S., (2010), Adsorption of dye from aqueous solution by cashew nut shell: Studies on equilibrium isotherm, kinetics and thermodynamics of interactions. Desalination. 261: 52–60.

[28] Zhong Q., Yue Q. Y., Li Q., Xu X., Gao B. Y., (2011), Preparation, characterization of modified wheat residue and its utilization for the anionic dye removal. Desalination. 267: 193–200.

[29] Jr W. J., Weber J. C. M., (1963), Kinetics of adsorption on carbon from solution. J. Sanit. Eng. Div. Am. Soc. Civ. Eng. 89: 31–60.

[30] Laaz I., Stébéa M., Benhamou A., Zoubir D., Blin J., (2016), Influence of porosity and surface modification on the adsorption of both cationic and anionic dyes. Colloids Surf. A: Physicochem. Eng. Aspects. 490: 30–40.

[31] Li W., Tang Y. , Zeng Y., Tong Z., Liang D., Cui W., (2012), Adsorption behavior of Cr (VI) ions on tannin-immobilized activated clay. Chem. Eng. J. 193: 88–95.                                     

[32] Inyinbor A. A., Adekola F. A., Olatunji G. A., (2016), Kinetics, isotherms and thermodynamic modeling of liquid phase adsorption of Rhodamine B dye onto Raphia hookerie fruit epicarp. Water. Resour. Ind. 15: 14-27.

[33] Anbia M., Salehi S., (2012), Removal of acid dyes from aqueous media by adsorption onto amino-functionalized nanoporous silica SBA-3. Dyes. Pigments. 94: 1-9.